| WTA Moscow | 10/19 16:45 | 26 | [23] Anastasia Pavlyuchenkova v Jankovic, Jelena [47] | 6-1,6-4 | |
| WTA Moscow | 10/18 11:30 | 25 | [23] Anastasia Pavlyuchenkova v Katerina Siniakova [52] | 7-6,5-7,7-5 | |
| WTA - Linz | 10/14 15:30 | 27 | [21] Anastasia Pavlyuchenkova v Cibulkova, Dominika [10] | 6-7,4-6 | |
| WTA - Linz | 10/13 13:00 | 26 | [21] Anastasia Pavlyuchenkova v Flipkens, Kirsten [59] | 6-4,7-6 | |
| WTA - Linz | 10/10 16:30 | 25 | [21] Anastasia Pavlyuchenkova v Anastasija Sevastova [31] | 6-4,6-1 | |
| Pékin, Chine | 10/02 10:20 | 24 | [17] Anastasia Pavlyuchenkova v Alison Riske [57] | 6-7,1-6 | |
| Wuhan, China | 09/26 04:00 | 24 | Anastasia Pavlyuchenkova v Doi, Misaki | Retired | |
| WTA Tokyo | 09/22 11:20 | 26 | Elina Svitolina v Anastasia Pavlyuchenkova | 7-6,6-4 | |
| WTA Tokyo | 09/20 08:20 | 25 | Petkovic, Andrea v Anastasia Pavlyuchenkova | Retired | |
| US Open 2016 Women | 09/03 20:15 | 25 | Karolina Pliskova v Anastasia Pavlyuchenkova | 6-2,6-4 | |
| US Open 2016 Women | 09/01 16:20 | 24 | Kristina Mladenovic v Anastasia Pavlyuchenkova | 2-6,6-4,6-7 | |
| US Open 2016 Women | 08/30 20:10 | 23 | Louisa Chirico v Anastasia Pavlyuchenkova | 1-6,4-6 | |
| WTA Montreal | 07/29 22:30 | 27 | Anastasia Pavlyuchenkova v Madison Keys | 6-7,6-1,0-6 | |
| WTA Montreal | 07/28 18:30 | 26 | Radwanska, Agnieszka v Anastasia Pavlyuchenkova | 4-6,7-6,1-6 | |
| WTA Montreal | 07/27 16:30 | 25 | Mchale, Christina v Anastasia Pavlyuchenkova | 2-6,5-7 | |
| WTA Montreal | 07/26 16:30 | 24 | Yulia Putintseva v Anastasia Pavlyuchenkova | 4-6,6-1,5-7 | |
| Wimbledon Women | 07/05 13:55 | 27 | Williams, Serena v Anastasia Pavlyuchenkova | 6-4,6-4 | |
| Wimbledon Women | 07/04 10:30 | 26 | Anastasia Pavlyuchenkova v Vandeweghe, Coco | 6-3,6-3 | |
| Wimbledon Women | 07/03 10:30 | 25 | Bacsinszky, Timea v Anastasia Pavlyuchenkova | 3-6,2-6 | |
| Wimbledon Women | 07/01 13:15 | 24 | Yulia Putintseva v Anastasia Pavlyuchenkova | 5-7,1-6 | |
| Wimbledon Women | 06/28 14:05 | 23 | Su-Wei Hsieh v Anastasia Pavlyuchenkova | 5-7,6-1,1-6 | |
| Billie Jean King Cup | 11/15 13:55 | 1 | Karolina Pliskova v Anastasia Pavlyuchenkova | 6-3,6-4 | |
| Billie Jean King Cup | 11/14 13:00 | 1 | Kvitova, Petra v Anastasia Pavlyuchenkova | 2-6,6-1,6-1 | |
| Wimbledon Women | 07/02 10:30 | 24 | Anastasia Pavlyuchenkova v Angelique Kerber | 5-7,2-6 | |
| Wimbledon Women | 06/30 10:30 | 23 | Anastasia Pavlyuchenkova v Mona Barthel | 6-7,7-6,6-2 | |
| Billie Jean King Cup | 04/18 13:05 | 1 | Anastasia Pavlyuchenkova v Lisicki, Sabine | 4-6,7-6,6-3 | |
| WTA Montreal | 08/05 16:00 | 24 | Anastasia Pavlyuchenkova v Venus Williams | 1-6,6-3,2-6 | |
| Wimbledon Women | 06/24 17:40 | 23 | Anastasia Pavlyuchenkova v Alison Riske | 6-4,5-7,1-6 |