| Hungarian Open 2020, MS, Qualification | 02/19 17:40 | - | Cedric Nuytinck v Shibaev, Alexander | W | 3-4 | |
| Tennis de table - Rencontres | 02/14 14:30 | 3 | Shibaev, Alexander v Panagiotis Gionis | L | 1-3 | |
| World Team Olympic Quals | 01/22 20:00 | - | Woojin Jang v Shibaev, Alexander | L | 3-0 | |
| Ligue des Champions | 01/17 17:35 | 3 | Panagiotis Gionis v Shibaev, Alexander | W | 2-3 | |
| Russia Premier League | 12/22 12:40 | - | Liventsov, Alexey v Shibaev, Alexander | L | 3-2 | |
| Russia Premier League | 12/21 12:49 | - | Shibaev, Alexander v Mikhail Butylev | W | 3-0 | |
| Russia Premier League | 12/21 05:52 | - | Shibaev, Alexander v Vladislav Samsonov | W | 3-0 | |
| Russia Premier League | 12/20 12:45 | - | Shibaev, Alexander v Nikulin, Ivan | W | 3-0 | |
| Russia Premier League | 12/20 05:03 | - | Ruslan Alchimbaev v Shibaev, Alexander | W | 0-3 | |
| Tennis de table - Rencontres | 12/09 19:30 | - | Maze, Michael v Shibaev, Alexander | W | 1-3 | |
| Tennis de table - Rencontres | 12/06 15:20 | - | Shibaev, Alexander v Simon Belik | W | 3-0 | |
| Austrian Open 2019, MS | 11/13 16:05 | - | Zhou, Yu v Shibaev, Alexander | L | 4-1 | |
| Ligue des Champions | 11/01 14:40 | - | Shibaev, Alexander v Dongsoo Kang | W | 3-0 | |
| Tennis de table - Rencontres | 10/25 16:30 | - | Dongsoo Kang v Shibaev, Alexander | W | 1-3 | |
| Tennis de table - Rencontres | 10/18 15:20 | - | Shibaev, Alexander v Allan Bentsen | W | 3-1 | |
| Swedish Open (WTP) 2019, MS, Qualification | 10/03 14:20 | 5 | Shibaev, Alexander v Sangsu Lee | L | 0-4 | |
| Swedish Open (WTP) 2019, MS, Qualification | 10/02 17:20 | - | Shibaev, Alexander v Viktor Brodd | W | 4-0 | |
| Swedish Open (WTP) 2019, MS, Qualification | 10/02 09:50 | - | Shibaev, Alexander v Zhai, Yujia | W | 4-3 | |
| Tennis de table - Rencontres | 09/12 16:00 | - | Ondrej Bajger v Shibaev, Alexander | W | 1-3 | |
| Euro Team Champs | 09/05 14:30 | 1 | Dimitrij Ovtcharov v Shibaev, Alexander | L | 3-2 | |
| Euro Team Champs | 09/03 18:30 | 1 | Shibaev, Alexander v Pavel Sirucek | W | 3-0 | |
| Euro Team Champs | 09/03 17:00 | 1 | Shibaev, Alexander v Lubomir Jancarik | W | 3-0 | |
| Czech Open | 08/24 14:45 | 3 | Shibaev, Alexander v Hugo Calderano | L | 1-4 | |
| Czech Open | 08/23 16:00 | 4 | Shibaev, Alexander v Ma, TE | W | 4-0 | |
| Czech Open | 08/22 18:30 | 5 | Liam Pitchford v Shibaev, Alexander | W | 2-4 | |
| Czech Open | 08/21 14:00 | - | Fegerl, Stefan v Shibaev, Alexander | W | 0-4 | |
| Czech Open | 08/20 15:25 | - | Salifou, Abdel-Kader v Shibaev, Alexander | W | 1-4 | |
| European Games | 06/24 16:00 | - | Kou, Lei v Shibaev, Alexander | L | 4-1 | |
| European Games | 06/23 17:00 | - | Mattias Falck v Shibaev, Alexander | W | 0-4 | |
| European Games | 06/22 17:00 | - | Shibaev, Alexander v Marek Badowski | W | 4-0 |