Round: 25 Ground: Clay
| Wimbledon, London, Great Britain | 2016/07/01 10:30 | Kyrgios, Nick v Brown, Dustin | 6-7,6-1,2-6,6-4,6-4 |
| Wimbledon, London, Great Britain | 2016/06/28 10:30 | Dusan Lajovic v Brown, Dustin | 6-4,3-6,6-3,3-6,4-6 |
| ATP Halle | 2016/06/15 15:50 | Baghdatis, Marcos v Brown, Dustin | 7-5,7-6 |
| ATP Halle | 2016/06/14 15:40 | Brown, Dustin v Albert Ramos-Vinolas | 6-3,7-5 |
| Open de France | 2016/05/25 10:25 | Sock, Jack v Brown, Dustin | 6-3,7-6,6-2 |
| Open de France | 2016/05/22 10:50 | Sela, Dudi v Brown, Dustin | 7-6,4-6,6-7,6-4,4-6 |
| French Open Qual | 2016/05/20 08:00 | Brown, Dustin v Brands, Daniel | 7-6,6-3 |
| French Open Qual | 2016/05/18 13:40 | Brown, Dustin v Calvin Hemery | 7-5,6-4 |
| Challenger Bastad | 2016/07/05 11:20 | Dustov, Farrukh v Munoz-De la Nava, Daniel | 4-6,6-2,6-2 |
| Wimbledon Qual | 2016/06/22 10:00 | Skugor, Franko v Munoz-De la Nava, Daniel | 7-6,6-2 |
| Wimbledon Qual | 2016/06/21 10:50 | Marsel Ilhan v Munoz-De la Nava, Daniel | 3-6,4-6 |
| Open de France | 2016/05/23 16:30 | Andrej Martin v Munoz-De la Nava, Daniel | 6-2,6-3,4-6,6-4 |
| Challenger - Heilbronn | 2016/05/10 16:00 | Munoz-De la Nava, Daniel v Nikoloz Basilashvili | 4-6,1-6 |
| ATP - Barcelone | 2016/04/19 11:30 | Granollers, Marcel v Munoz-De la Nava, Daniel | 6-4,6-3 |
| ATP - Marrakech | 2016/04/04 10:00 | Gonzalez, Maximo v Munoz-De la Nava, Daniel | 6-1,6-4 |
| ATP - Buenos Aires | 2016/02/09 17:00 | Gastao Elias v Munoz-De la Nava, Daniel | 4-6,6-4,6-1 |