| German Open 2020, WS | 2020/01/30 14:00 | Xiaona Shan v Liu, Shiwen | L | 0-4 |
| German Open 2020, WS | 2020/01/29 10:10 | Xiaona Shan v Noskova, Yana | W | 4-3 |
| German Open 2020, WS | 2020/01/28 13:15 | Xiaona Shan v Camila Arguelles | W | 4-0 |
| Ligue des Champions - Femmes | 2020/01/10 18:40 | Silvia Erdelyi De Souza v Xiaona Shan | W | 0-3 |
| Ligue des Champions - Femmes | 2019/11/29 17:30 | Xiaona Shan v Andrea Todorovic | W | 3-0 |
| Austrian Open 2019, WS | 2019/11/13 15:15 | Xiaona Shan v Rui Zhang | L | 2-4 |
| Austrian Open 2019, WS | 2019/11/12 12:00 | Leonie Hartbrich v Xiaona Shan | W | 0-4 |
| Ligue des Champions - Femmes | 2019/10/22 19:00 | Andrea Todorovic v Xiaona Shan | W | 0-3 |
| Oman Open U21 Women | 2020/02/06 09:00 | Grigelova, Natalia v Elizabet Abraamian | L | 0-3 |
| Belarus Open Women | 2019/10/30 07:25 | Grigelova, Natalia v Semenova, Daria | L | 1-3 |
| Oman Open U21 Women | 2019/10/16 08:40 | Grigelova, Natalia v Marie Migot | L | 0-3 |
| Serbia Open U21 Women | 2019/05/01 13:45 | Feredj, Hiba v Grigelova, Natalia | W | 1-3 |
| Serbia Open U21 Women | 2019/05/01 07:35 | Cote, Alicia v Grigelova, Natalia | W | 0-3 |
| République tchèque - Extraleague | 2019/04/13 16:00 | Miroslava Saglova v Grigelova, Natalia | L | 3-2 |
| République tchèque - Extraleague | 2019/03/21 09:40 | Deshpande, Divya v Grigelova, Natalia | L | 3-1 |
| République tchèque - Extraleague | 2019/03/20 06:40 | Yousra Helmy v Grigelova, Natalia | L | 3-1 |