Stadium: Estadio Round: 25 Ground: Hardcourt outdoor
| ITF W25 Daytona Beach | 2019/01/16 18:10 | Irene Burillo Escorihuela v Ann Li | 4-6,4-6 |
| ITF - W100 Irapuato | 2024/02/06 19:00 | Adriana Reami v Ann Li | 6-2,6-1 |
| ITF - W75 Rome (GA) | 2024/01/31 19:05 | Ann Li v Elizabeth Ionescu | 0-6,3-6 |
| Open d'Australie - Femmes | 2024/01/11 05:00 | Ann Li v Daria Snigur | 4-6,2-6 |
| Open d'Australie - Femmes | 2024/01/10 01:50 | Ann Li v Tereza Martincova | 6-7,6-4,6-4 |
| WTA Canberra | 2023/12/31 06:50 | Petra Hule v Ann Li | 7-5,6-7,6-4 |
| ITF W100 Charleston | 2023/11/10 19:00 | Ann Li v Renata Zarazua | 4-6,1-6 |
| ITF W100 Charleston | 2023/11/09 14:50 | Ann Li v Sophie Chang | 3-6,6-4,6-3 |
| ITF W100 Charleston | 2023/11/07 18:45 | Ann Li v Yulia Starodubtsewa | 7-5,6-4 |
| ITF - W100 Irapuato | 2024/02/07 03:00 | Contreras Gomez, Fernanda v Irene Burillo Escorihuela | 7-6,6-3 |
| ITF - W35 Monastir | 2024/01/26 08:30 | Irene Burillo Escorihuela v Lucija Ciric Bagaric | 0-6,2-6 |
| ITF - W35 Monastir | 2024/01/25 08:30 | Irene Burillo Escorihuela v Malene Helgo | 6-2,6-1 |
| ITF - W35 Monastir | 2024/01/23 10:30 | Irene Burillo Escorihuela v Hanne Vandewinkel | 6-3,1-6,7-6 |
| ITF - W35 Monastir | 2024/01/19 11:00 | Polina Iatcenko v Irene Burillo Escorihuela | 6-1,7-5 |
| ITF - W35 Monastir | 2024/01/18 08:30 | Oana Gavrila v Irene Burillo Escorihuela | 2-6,3-6 |
| ITF - W35 Monastir | 2024/01/17 08:30 | Stefania Bojica v Irene Burillo Escorihuela | 1-6,3-6 |
| WTA Andorra | 2023/11/28 17:00 | Anastasija Sevastova v Irene Burillo Escorihuela | 6-7,6-2,6-1 |