Stadium: Court 6 Round: 54 Ground: Hardcourt outdoor
| ITF - W15 Héraklion | 2022/10/12 09:30 | Popescu, Anna v Sevil Yuldasheva | 5-7,2-6 |
| ITF - W15 Héraklion | 2022/10/11 06:30 | Popescu, Anna v Julia Victoria Rennert | 6-4,7-5 |
| UK Pro League Women | 2022/08/31 11:15 | Popescu, Anna v Summer Yardley | 7-5,5-7,7-10 |
| UK Pro League Women | 2022/08/29 14:30 | Eliz Maloney v Popescu, Anna | 6-2,6-0 |
| ITF W25 Roehampton | 2022/08/21 13:15 | Katie Stresnakova v Popescu, Anna | 6-2,6-2 |
| ITF W25 Aldershot | 2022/08/14 14:30 | Blake, Angelica v Popescu, Anna | 6-1,6-0 |
| ITF W25 Loughborough | 2022/01/23 10:00 | Talia Neilson Gatenby v Popescu, Anna | 4-6,6-1,10-6 |
| ITF W15 Sozopol | 2021/10/04 11:00 | Eleni Christofi v Popescu, Anna | 6-0,6-3 |
| UK Pro League Women | 2023/04/14 16:00 | Alessia Popescu v Michelle Dzjachangirova | 6-7,6-4,7-10 |
| UK Pro League Women | 2023/04/13 10:00 | Alessia Popescu v Summer Yardley | 3-6,1-6 |
| UK Pro League Women | 2023/04/12 09:30 | Eliz Maloney v Alessia Popescu | 6-1,6-0 |
| UK Pro League Women | 2023/04/10 11:15 | Alice Gillan v Alessia Popescu | 6-4,6-4 |
| ITF W25 Bath | 2023/02/05 17:00 | Alessia Popescu v Michaela Laki | 2-6,3-6 |
| ITF W25 Loughborough | 2023/01/08 13:30 | Katie Stresnakova v Alessia Popescu | 6-2,6-1 |
| ITF W15 Castellon | 2022/10/30 10:30 | Blanca Pico Navarro v Alessia Popescu | 6-0,6-4 |
| ITF - W15 Sharm El Sheikh | 2022/10/11 10:20 | Alessia Popescu v Patricija Paukstyte | 1-6,2-6 |